ЭТИЛЕННИ КИСЛОРОД ИШТИРОКИДА ВОДОРОД ХЛОРИД ТАЪСИРИДА ОКСИХЛОРЛАШ ЖАРАЁНИ ТЕРМОДИНАМИКАСИ
Аннотация
Этиленнинг кислород иштирокида водород хлорид таъсирида оксихлорланиш жараёнларининг термодинамикаси ўрганилган ва оксихлорлаш реакциясининг бориш механизми таклиф этилган. Жараённинг механизмини боришини ўрганиш асосида 1,2-дихлорэтан ва карбонат ангидрид ҳосил бўлиш тезлигини тавсифловчи кинетик тенгламалар таклиф этилган. Этиленни водород хлорид билан кислород иштирокида оксихлорланиш реакциясини амалга ошириш учун олинган катализаторлар иштирокида этиленни водород хлорид билан кислород иштирокида оксихлорлашнинг тўлиқ оксидланиш маҳсулотларини ҳосил бўлишининг қонуниятлари этиленни водород хлорид таъсирида кислород иштирокида оксихлорланиш реакциясини ўтказиш учун мўлжалланган оқимли суюқ қатламли реакторда ўрганилди. Ҳарорат диапазони 210-240 °C, газларнинг чизиқли тезлиги 5,5-7 см/сек, шартли этиленни кислород иштирокида водород хлорид билан оксихлорлаш реакциясининг контакт вақти 8,5-9,5 сек. Этиленни оксихлорловчи реактор баландлиги 32,5м диаметри 3,5м колоннали аппаратидан иборат. Этиленни водород хлорид таъсирида кислород иштирокида оксихлорланиш учун мўлжалланган реакторининг иш режимлари аниқланди ва оксихлорлаш реакциясини амалга ошириш учун мўлжалланган реакторнинг моддий ва иссиқлик баланси ҳисобланди.
Библиографические ссылки
Lin, R.; Amrute, A. P.; Perez-Ramirez, J. Halogen-Mediated Conversion of Hydrocarbons to Commodities. Chem. Rev. 2017, 117, 4182−4247.
Davies, C. J.; Miedziak, P. J.; Brett, G. L.; Hutchings, G. J. Vinyl Chloride Monomer Production Catalysed by Gold: A Review. Chin. J.Catal 2016, 37, 1600−1607.
Global Production Capacity of Vinyl Chloride Monomer 2018 & 2023. Published by M. Garside. https://www.statista.com/statistics/1063677/global-vinyl-chloride-monomer-production-capacity/ (accessed 2019-11-06).
Xu, H.; Luo, G. H. Green Production of PVC From Laboratory to Industrialization: State-of-the-art Review of Heterogeneous Non- Mercury Catalysts for Acetylene Hydrochlorination. J. Ind. Eng. Chem. 2018, 65, 13−25.
Chemmangattuvalappil, N. G.; Chon, C. H.; Sum, D. N. K.; Elyas, R.; Chen, C.-L.; Chien, I. L.; Lee, H.-Y.; Elms, R. D. Chemical Engineering Process Simulation; Elsevier: 2017.
Kurta, S.; Mykytyn, I.; Khatsevich, O.; Ribun, V. Mechanism of Catalytic Additive Chlorination of Ethylene to 1, 2-Dichloroethane. Theor. Exp. Chem. 2018, 54, 283−291.
Hickman, D. A.; Jones, M. E.; Jovanovic, Z. R.; Olken, M. M.; Podkolzin, S. G.; Stangland, E. E.; Thompson, R. K. Reactor Scale-up for Fluidized Bed Conversion of Ethane to Vinyl Chloride. Ind. Eng. Chem. Res. 2010, 49, 10674−10681.
Boulamanti, A.; Moya, J. Energy efficiency and GHG emissions: Prospective scenarios for the Chemical and Petrochemical Industry; Publications Office of the European Union: 2017; DOI: 10.2760/630308.
Scharfe, M.; Lira-Parada, P. A.; Paunovic, V.; Moser, M.; Amrute, A. P.; Perez-Ramirez, J. Oxychlorination-Dehydrochlorination Chemistry on Bifunctional Ceria Catalysts for Intensified Vinyl Chloride Production. Angew. Chem., Int. Ed. 2016, 55, 3068−3072.
Higham, M. D.; Scharfe, M.; Capdevila-Cortada, M.; Perez-Ramirez, J.; Lopez, N. Mechanism of Ethylene Oxychlorination over Ruthenium Oxide. J. Catal. 2017, 353, 171−180.
Scharfe, M.; Lira-Parada, P. A.; Amrute, A. P.; Mitchell, S.; Perez-Ramirez, J. Lanthanide Compounds as Catalysts for the One-Step Synthesis of Vinyl Chloride from Ethylene. J. Catal. 2016, 344, 524−534.
Scharfe, M.; Capdevila-Cortada, M.; Kondratenko, V. A.; Kondratenko, E. V.; Colussi, S.; Trovarelli, A.; Lopez, N.; Perez-Ramirez, J. Mechanism of Ethylene Oxychlorination on Ceria. ACS Catal. 2018, 8, 2651−2663.
Louwerse, M. J.; Rothenberg, G. Modeling Catalyst Preparation: The Structure of Impregnated−Dried Copper Chloride on γ-Alumina at Low Loadings. ACS Catal. 2013, 3, 1545−1554.
Muddada, N. B.; Olsbye, U.; Caccialupi, L.; Cavani, F.; Leofanti, G.; Gianolio, D.; Bordiga, S.; Lamberti, C. Influence of Additives in Defining the Active Phase of The Ethylene Oxychlorination Catalyst. Phys. Chem. Chem. Phys. 2010, 12, 5605−5618.
Qi, Y.; Fenes, E.; Ma, H.; Wang, Y.; Rout, K. R.; Fuglerud, T.; Piccinini, M.; Chen, D. Origin of Potassium Promotion Effects on CuCl2/γ-Al2O3 Catalyzed Ethylene Oxychlorination. Appl. Surf. Sci. 2020, 521, 146310.
Qi, Y.; Fenes, E.; Ma, H.; Wang, Y.; Rout, K. R.; Fuglerud, T.; Piccinini, M.; Chen, D. Cluster-Size-Dependent Interaction between Ethylene and CuCl2 Clusters Supported via γ-Alumina. J. Phys. Chem. C 2020, 124, 10430−10440.
Mamadoliev, I.I., Fayzullaev, N.I., Khalikov, K.M. Synthesis of high silicon of zeolites and their sorption properties//International Journal of Control and Automation, 2020, 13(2), стр. 703–709.
Mamadoliev, I.I., Fayzullaev, N.I. Optimization of the activation conditions of high silicon zeolite//International Journal of Advanced Science and Technology, 2020, 29(3), стр. 6807–6813
F N Temirov, J Kh Khamroyev, N I Fayzullayev, G Sh Haydarov and M Kh Jalilov. Hydrothermal synthesis of zeolite HSZ-30 based on kaolin //IOP Conference Series: Earth and Environmental Science. – IOP Publishing, 2021. – Т. 839. – №. 4. – С. 042099.
Fayzullayev, N.I., Umirzakov, R.R., Pardaeva, S.B. Study of acetylating reaction of acetylene by gas chromatographic method//ACS National Meeting Book of Abstracts, 2005, 229(2)
Fajzullaev, N.I., Muradov, K.M. Investigation of reaction of catalytic vapor-phase synthesis of vinyl acetate on applied catalyst//Khimicheskaya Promyshlennost', 2004, (3), стр. 136–139
Fayzullayev, N.I., Umirzakov, R.R. To obtain acetone by spontaneous hydration of acetylene//ACS National Meeting Book of Abstracts, 2005, 229(2)
Fajzullaev, N.I., Yusupov, D., Shirinov, Kh.Sh, Keremetskaya, L.V, Umirzakov, R.R. Catalytic vapor-phase hydration of acetylene and its derivatives//Khimicheskaya Promyshlennost', 2002, (7), стр. 34–37
Fajzullaev, N.I. Kinetics and mechanism of reaction of catalytic hydrochlorination of acetylene//Khimicheskaya Promyshlennost', 2004, (1), стр. 49–52
Aslanov, S.C., Buxorov, A.Q., Fayzullayev, N.I. Catalytic synthesis of С2-С4-alkenes from dimethyl ether// International Journal of Engineering Trends and Technology, 2021, 69(4), стр. 67–75
Xolmirzayeva H. N., Fayzullayev N. I. Obtaining Nanocarbon from Local Raw Materials and Studying Its Textural and Sorption Properties //International Journal of Engineering Trends and Technology, 2022 Volume 70 Issue 2, 163-171. ISSN: 2231 – 5381 /doi:10.14445/22315381/IJETT-V70I2P219
Kurbanova D., Fayzullayev N., Bobomurodova S. Determination of optimal conditions and kinetic laws of hydrogen chloride separation reaction from simm-dichloroethane (1,2-dichloroethane)// E3S Web of Conferences 460, 10028 (2023) https://doi.org/10.1051/e3sconf/202346010028 BFT-2023
Fayzullayev N., Kurbanova D., Bobomurodova S. Obtaining vinyl chloride by oxychlorination of ethylene under the action of hydrogen chloride in the presence of oxygen // E3S Web of Conferences 460, 10023 (2023) https://doi.org/10.1051/e3sconf/202346010023 BFT-2023
Bukhorov A. Q., Aslanov S. C., Fayzullaev N. I. Catalyst deactivation in synthesis of olefins below methanol //AIP Conference Proceedings. – AIP Publishing LLC, 2022. – Т. 2432. – №. 1. – С. 050010.
Bukhorov A. Q., Aslanov S. C., Fayzullaev N. I. Conversion of dimethyl ether to lower olefines //AIP Conference Proceedings. – AIP Publishing LLC, 2022. – Т. 2432. – №. 1. – С. 050011.
Bukhorov A. Q., Aslanov S. C., Fayzullaev N. I. Kinetic laws of dimethyl ether synthesis in synthesis gas //AIP Conference Proceedings. – AIP Publishing LLC, 2022. – Т. 2432. – №. 1. – С. 050012.
АДЫГЕЗАЛОВА, М. (2022). ... HÜSNÜ-XUDA ŞAİRİYİM» ИЛИ К ВОПРОСУ О СИНТЕЗЕ ВОСТОЧНОЙ И ЕВРОПЕЙСКОЙ ЛИТЕРАТУР В ДРАМЕ Г. ДЖАВИДА «ПРОРОК. Turkology, (1).
Адыгезалова, М. Н. (2020). Из опыта хронологического описания драм Г. Джавида. Редакционная коллегия, 106.
Gizi, A. M. N. (2021). Features of romanticism as a literary direction (based on the works of russian literary critics). ACADEMICIA: An International Multidisciplinary Research Journal, 11(3), 288-294.
ADIGEZALOVA, M. (2021). THE" WOMENS QUESTION" IN THE VIEWS OF A. CHULPAN AND G. JAVID. THEORETICAL & APPLIED SCIENCE Учредители: Теоретическая и прикладная наука, (10), 1028-1032.
ТАРБИЯ, О., & ҚАРАШЛАРИ, М. (2020). ВЗГЛЯДЫ АЗЕРБАЙДЖАНСКОГО ПРОСВЕТИТЕЛЯ НА ПРОБЛЕМЫ ОБРАЗОВАНИЯ И ВОСПИТАНИЯ. Adigezalova, MN.
Adigezalova, M. N. (2020). Gender and art in the XVII–XIX centuries. ISJ Theoretical & Applied Science, 05 (85), 655-658.
Adigezalova, M. N., & Adigezalova, M. N. (2018). THE INTERPRETATION OF SAHIBKIRAN’S FIGURE IN G. DJAVID’S DRAMA “TEMUR LAME” AND MUHAMMAD ALI’S EPIC NOVEL “AMIR TEMUR THE GREAT”. ISJ Theoretical & Applied Science, 3(59), 78-80.
